Layered double hydroxides (LDHs) otherwise referred as hydrotalcite-like (HTlike)
materials are potential sorbents that are explored widely in the field of waste water
remediation of noxious anions. The structural features of LDHs makes them effective
sorbents for these anions through different mechanism like surface adsorption, anionexchange,
reconstruction and surface precipitation. This chapter presents a discussion about
LDHs, their synthesis methodologies, physicochemical characterization and their potential
in the removal of environmentally undesired oxoanions like phosphate, borate and
chromate from aqueous solutions. The optimization of the various parameters like sorbate
concentration, pH, temperature, time, extent of removal in the co-presence of competitive
anions and reusability are discussed in respective sections. A comparison of the anionexchange
capacity of LDHs with commercial anion exchangers is also discussed. Different
mechanisms involved in the removal of phosphate, borate and chromate anions by LDHs
are addressed.
Keywords: Layered double hydroxides (LDHs), Sorbent, Water remediation,
Oxoanions, Hydrotalcite-like compounds, Co-precipitation, Adsorption isotherm,
Physicochemical characterization, Anion exchange, Desorption.
