Title:Synthesis and Electrochemical Applications of Carbon Nano-onions
Volume: 20
Issue: 1
Author(s): Jorge A. Castaño, Jolaine G. Betancourth, Dahiana L. Caicedo, Renso Visbal and Manuel N. Chaur*
Affiliation:
- Departamento de Química, Universidad del Valle, AA 25360, Cali, Colombia
- Centro de Excelencia en Nuevos
Materiales (CENM), Universidad del Valle, AA 25360, Cali, Colombia
Keywords:
Carbon nano-onion, doped nanomaterial, supercapacitor, electrocatalyst, electrochemical sensor, HR-TEM.
Abstract: Carbon nano-onions, a family of carbon nanomaterials, consist of multiple concentric fullerene-
like carbon shells which are highly defective and disordered. Due to their unique physicochemical
properties, such as high conductivity, high surface area, biocompatibility, thermal stability, and
others, they are promising nanomaterials for different electrochemical applications. In this sense, this
review outlines the synthetic methods available to afford carbon nano-onions in their pristine, functionalized
(covalent and non covalent) and doped forms and their use in energy storage, electrocatalysis
and sensing. Particularly, we review the performance and properties of carbon nano-onions as electrode
materials for supercapacitors, electrocatalysts in different reactions for fuel cells, and electrode
materials for sensors. In the last decade, as we will discuss, scientists have found that functionalized
and doped carbon nano-onions have better electrochemical properties than pristine carbon nanoonions,
such as specific capacitance, surface wettability, energy power, adsorption on an electrode
surface, and charge delocalization, among others.