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Current Analytical Chemistry

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ISSN (Print): 1573-4110
ISSN (Online): 1875-6727

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Research Article

Extraction and Analysis of Microplastic Beads from Personal Care Products

Author(s): Pinal S. Bhavsar and Anil H. Gore*

Volume 19, Issue 2, 2023

Published on: 05 December, 2022

Page: [184 - 189] Pages: 6

DOI: 10.2174/1573411019666221020094611

Abstract

Background: Nowadays, plastic accumulation in marine has become one of the topics of global concern, with emerging research efforts focusing on the threat of microbeads (<5mm). A source of microplastic pollution is derived from personal care products (facial cleanser) that contain polyethylene microplastic (microbeads), which are not captured by the wastewater treatment plant. These small particles are especially concerning because of their potential to translocate in the bodies of organisms.

Methods: Herein, we have used a mixture of hydrogen peroxide with nitric acid to dissolve the organic matter before the filtration and filtration was carried out by using Whatman filter paper 42 to ascertain that all the microbeads had been collected. Collected microbeads were identified using Fouriertransformed infrared spectroscopy (FT-IR) and stereo microscope.

Results: In this study, we have observed that personal care products contain microplastic beads, and that three out of six personal care products contain a polyethylene (PE) bead.

Conclusion: We have provided a feasible separation and analysis method for microplastic beads in personal care products.

Keywords: Microplastic, microbeads, personal care products, extraction, FT-IR, stereo microscope.

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[1]
Ritchie, H.; Roser, M. Plastic pollution; Our World in Data; , 2018. Available from: https://ourworldindata.org/plastic-pollution
[2]
Moore, C.J. Synthetic polymers in the marine environment: A rapidly increasing, long-term threat. Environ. Res., 2008, 108(2), 131-139.
[http://dx.doi.org/10.1016/j.envres.2008.07.025] [PMID: 18949831]
[3]
Cole, M.; Lindeque, P.; Halsband, C.; Galloway, T.S. Microplastics as contaminants in the marine environment: A review. Mar. Pollut. Bull., 2011, 62(12), 2588-2597.
[http://dx.doi.org/10.1016/j.marpolbul.2011.09.025] [PMID: 22001295]
[4]
Andrady, A.L. Microplastics in the marine environment. Mar. Pollut. Bull., 2011, 62(8), 1596-1605.
[http://dx.doi.org/10.1016/j.marpolbul.2011.05.030] [PMID: 21742351]
[5]
Zitko, V.; Hanlon, M. Another source of pollution by plastics: Skin cleaners with plastic scrubbers. Mar. Pollut. Bull., 1991, 22(1), 41-42.
[http://dx.doi.org/10.1016/0025-326X(91)90444-W]
[6]
Fendall, L.S.; Sewell, M.A. Contributing to marine pollution by washing your face: Microplastics in facial cleansers. Mar. Pollut. Bull., 2009, 58(8), 1225-1228.
[http://dx.doi.org/10.1016/j.marpolbul.2009.04.025] [PMID: 19481226]
[7]
Cheung, P.K.; Fok, L. Characterisation of plastic microbeads in facial scrubs and their estimated emissions in Mainland China. Water Res., 2017, 122, 53-61.
[http://dx.doi.org/10.1016/j.watres.2017.05.053] [PMID: 28591661]
[8]
Napper, I.E.; Bakir, A.; Rowland, S.J.; Thompson, R.C. Characterisation, quantity and sorptive properties of microplastics extracted from cosmetics. Mar. Pollut. Bull., 2015, 99(1-2), 178-185.
[http://dx.doi.org/10.1016/j.marpolbul.2015.07.029] [PMID: 26234612]
[9]
Rosette, J.L.; Yablonski, J.; Mancuso, S.; Kale, G. Packaging, cosmetics and pharmaceuticals. In: Kirk‐Othmer Encyclopedia of Chemical Technology;; 1-14.
[10]
Mills, O.H., Jr; Kligman, A.M. Evaluation of abrasives in acne therapy. Cutis, 1979, 23(5), 704-705.
[PMID: 156627]
[11]
Habib, R.Z.; Salim Abdoon, M.M.; Al Meqbaali, R.M.; Ghebremedhin, F.; Elkashlan, M.; Kittaneh, W.F.; Cherupurakal, N.; Mourad, A.H.I.; Thiemann, T.; Al Kindi, R. Analysis of microbeads in cosmetic products in the United Arab Emirates. Environ. Pollut., 2020, 258, 113831.
[http://dx.doi.org/10.1016/j.envpol.2019.113831] [PMID: 31874431]
[12]
Duis, K.; Coors, A. Microplastics in the aquatic and terrestrial environment: Sources (with a specific focus on personal care products), fate and effects. Environ. Sci. Eur., 2016, 28(1), 2.
[http://dx.doi.org/10.1186/s12302-015-0069-y] [PMID: 27752437]
[13]
Tanaka, K.; Takada, H. Microplastic fragments and microbeads in digestive tracts of planktivorous fish from urban coastal waters. Sci. Rep., 2016, 6(1), 34351.
[http://dx.doi.org/10.1038/srep34351] [PMID: 27686984]
[14]
Murphy, F.; Ewins, C.; Carbonnier, F.; Quinn, B. Wastewater Treatment Works (WwTW) as a source of microplastics in the aquatic environment. Environ. Sci. Technol., 2016, 50(11), 5800-5808.
[http://dx.doi.org/10.1021/acs.est.5b05416] [PMID: 27191224]
[15]
Carr, S.A.; Liu, J.; Tesoro, A.G. Transport and fate of microplastic particles in wastewater treatment plants. Water Res., 2016, 91, 174-182.
[http://dx.doi.org/10.1016/j.watres.2016.01.002] [PMID: 26795302]
[16]
Peters, C.A.; Bratton, S.P. Urbanization is a major influence on microplastic ingestion by sunfish in the Brazos River Basin, Central Texas, USA. Environ. Pollut., 2016, 210, 380-387.
[17]
Godoy, V.; Martín-Lara, M.A.; Calero, M.; Blázquez, G. Physical-chemical characterization of microplastics present in some exfoliating products from Spain. Mar. Pollut. Bull., 2019, 139, 91-99.
[http://dx.doi.org/10.1016/j.marpolbul.2018.12.026] [PMID: 30686453]
[18]
Lei, K.; Qiao, F.; Liu, Q.; Wei, Z.; Qi, H.; Cui, S.; Yue, X.; Deng, Y.; An, L. Microplastics releasing from personal care and cosmetic products in China. Mar. Pollut. Bull., 2017, 123(1-2), 122-126.
[http://dx.doi.org/10.1016/j.marpolbul.2017.09.016] [PMID: 28911870]
[19]
Chang, M. Reducing microplastics from facial exfoliating cleansers in wastewater through treatment versus consumer product decisions. Mar. Pollut. Bull., 2015, 101(1), 330-333.
[http://dx.doi.org/10.1016/j.marpolbul.2015.10.074] [PMID: 26563542]
[20]
So, W.K.; Chan, K.; Not, C. Abundance of plastic microbeads in Hong Kong coastal water. Mar. Pollut. Bull., 2018, 133, 500-505.
[http://dx.doi.org/10.1016/j.marpolbul.2018.05.066] [PMID: 30041343]
[21]
Praveena, S.M.; Shaifuddin, S.N.M.; Akizuki, S. Exploration of microplastics from personal care and cosmetic products and its estimated emissions to marine environment: An evidence from Malaysia. Mar. Pollut. Bull., 2018, 136, 135-140.
[http://dx.doi.org/10.1016/j.marpolbul.2018.09.012] [PMID: 30509794]
[22]
Guerranti, C.; Martellini, T.; Perra, G.; Scopetani, C.; Cincinelli, A. Microplastics in cosmetics: Environmental issues and needs for global bans. Environ. Toxicol. Pharmacol., 2019, 68, 75-79.
[http://dx.doi.org/10.1016/j.etap.2019.03.007] [PMID: 30877953]
[23]
Gulmine, J.V.; Janissek, P.R.; Heise, H.M.; Akcelrud, L. Polyethylene characterization by FTIR. Polym. Test., 2002, 21(5), 557-563.
[http://dx.doi.org/10.1016/S0142-9418(01)00124-6]
[24]
Fries, E.; Dekiff, J.H.; Willmeyer, J.; Nuelle, M.T.; Ebert, M.; Remy, D. Identification of polymer types and additives in marine microplastic particles using pyrolysis-GC/MS and scanning electron microscopy. Environ. Sci. Process. Impacts, 2013, 15(10), 1949-1956.
[http://dx.doi.org/10.1039/c3em00214d] [PMID: 24056666]
[25]
Gallo, F.; Fossi, C.; Weber, R.; Santillo, D.; Sousa, J.; Ingram, I.; Nadal, A.; Romano, D. Marine litter plastics and microplastics and their toxic chemicals components: the need for urgent preventive measures. Environ. Sci. Eur., 2018, 30(1), 13.
[http://dx.doi.org/10.1186/s12302-018-0139-z] [PMID: 29721401]
[26]
Eriksen, M.; Lebreton, L.C.M.; Carson, H.S.; Thiel, M.; Moore, C.J.; Borerro, J.C.; Galgani, F.; Ryan, P.G.; Reisser, J. Plastic pollution in the world’s oceans: More than 5 trillion plastic pieces weighing over 250,000 tons afloat at sea. PLoS One, 2014, 9(12), e111913.
[http://dx.doi.org/10.1371/journal.pone.0111913] [PMID: 25494041]
[27]
Yang, J.; Qiu, K. Preparation of activated carbons from walnut shells via vacuum chemical activation and their application for methylene blue removal. Chem. Eng. J., 2010, 165(1), 209-217.
[http://dx.doi.org/10.1016/j.cej.2010.09.019]

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