Highly Efficient and Selective Addition of Hydroxylamine to Nitriles in Ionic Liquids

ISSN: 1875-6271 (Online)
ISSN: 1570-1794 (Print)


Volume 11, 6 Issues, 2014


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Prof. Eduardo A Castro
Universidad Nacional de La Plata
Buenos Aires
Argentina


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Highly Efficient and Selective Addition of Hydroxylamine to Nitriles in Ionic Liquids

Author(s): Attila Voros, Zoltan Baan, Geza Timari, Istvan Hermecz, Peter Mizsey and Zoltan Finta

Affiliation: Sanofi C&BD, To u. 1-5., H-1045, Budapest, Hungary and Budapest University of Technology and Economics, Department of Chemical and Environmental Process Engineering, Budafoki ut 8., H-1111, Budapest, Hungary.

Abstract

The solvent effect of different imidazolium, phosphonium and quaternary ammonium based ionic liquids was studied for the synthesis of amidoximes, demonstrating enhanced selectivity when using IL’s as the reaction medium.




Keywords: Amidoxime, benzonitriles, green chemistry, hydroxylamine, ionic liquid, selective synthesis.

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Article Details

Volume: 11
Issue Number: 5
First Page: 751
Last Page: 756
Page Count: 6
DOI: 10.2174/15701794113106660082
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