Bismuth Nitrate Catalyzed Microwave Assisted Aza-Diels Alder Reaction for Synthesis of Bicyclo[2,2,2]-Octanones Scaffold

ISSN: 2213-3364 (Online)
ISSN: 2213-3356 (Print)


Volume 1, 2 Issues, 2014






Current Microwave Chemistry

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Editor-in-Chief:
Bimal K. Banik
Department of Chemistry
College of Science & Mathematics
The University of Texas-Pan American
1201 West University Drive
Edinburg, Texas
USA


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Bismuth Nitrate Catalyzed Microwave Assisted Aza-Diels Alder Reaction for Synthesis of Bicyclo[2,2,2]-Octanones Scaffold

Author(s): Ram Naresh Yadav, Ashwini Bobbala, Sunena Chandra and Bimal K. Banik

Affiliation: Department of Chemistry, The University of Texas Pan American, 1201 West University Drive, Edinburg, Texas 78539, USA.

Abstract

Bismuth nitrate-catalyzed microwave-assisted one-pot three components Aza-Diels-Alder reaction has been investigated. This method has been used for an efficient synthesis of 2-azabicyclo[2,2,2] cyclooctanones.




Keywords: Alkaloids, aza-Diels-Alder, azabicycle, bismuth nitrate, cycloadducts, diastereoselectivity, dienophile, endo/exo, heterocycles, in situ, keto-enol tautomerization, Lewis acid, microwave chemistry, natural product, one-pot chemistry.

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Article Details

Volume: 1
Issue Number: 2
First Page: 94
Last Page: 97
Page Count: 4
DOI: 10.2174/2213335601666140630165348
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